The first ship carrying Ukrainian grain has set off from the port of Odesa, Turkey's defence ministry said Monday.
The Sierra Leone-flagged cargo ship, Razoni left the port of Odesa for Lebanon, the ministry said.
A statement from the United Nations said the Razoni is carrying over 26,000 tonnes of corn.
The ship is expected to reach Istanbul on Tuesday, where it will be inspected, before being allowed to proceed to Lebanon, the ministry said.
Russia and Ukraine signed separate agreements with Turkey and the U.N. clearing the way for Ukraine — one of the world's key breadbaskets — to export 22 million tonnes of grain and other agricultural goods that have been stuck in Black Sea ports because of Russia's invasion.
The deals also allow Russia to export grain and fertilisers.
Turkey's defence ministry says the first ship carrying Ukrainian grain will set off from the port of Odesa on Monday.
The ministry says the Sierra Leone-flagged cargo ship, Razoni, which has been loaded with corn, will depart Odesa for Lebanon.
The ministry statement said other ships would also depart Ukraine's ports through the safe corridors in line with deals signed in Istanbul on July 22, but did not provide further details.